Bose-Einstein condensate (BEC), a state of matter in which separate atoms or subatomic particles, cooled to near absolute zero (0 K, − 273.15 °C, or − 459.67 °F; K = kelvin), coalesce into a single quantum mechanical entity—that is, one that can be described by a wave function—on a near-macroscopic scale. This form of matter was predicted in 1924 by Albert Einstein on the basis of the quantum formulations of the Indian physicist Satyendra Nath Bose.
Although it had been predicted for decades, the first atomic BEC was made only in 1995, when Eric Cornell and Carl Wieman of JILA, a research institution jointly operated by the National Institute of Standards and Technology (NIST) and the University of Colorado at Boulder, cooled a gas of rubidium atoms to 1.7 × 10−7 K above absolute zero. Along with Wolfgang Ketterle of the Massachusetts Institute of Technology (MIT), who created a BEC with sodium atoms, these researchers received the 2001 Nobel Prize for Physics. Research on BECs has expanded the understanding of quantum physics and has led to the discovery of new physical effects.
BEC theory traces back to 1924, when Bose considered how groups of photons behave. Photons belong to one of the two great classes of elementary or submicroscopic particles defined by whether their quantum spin is a nonnegative integer (0, 1, 2, …) or an odd half integer (1/2, 3/2, …). The former type, called bosons, includes photons, whose spin is 1. The latter type, called fermions, includes electrons, whose spin is 1/2.
As Bose noted, the two classes behave differently (see Bose-Einstein and Fermi-Dirac statistics). According to the Pauli exclusion principle, fermions tend to avoid each other, for which reason each electron in a group occupies a separate quantum state (indicated by different quantum numbers, such as the electron’s energy). In contrast, an unlimited number of bosons can have the same energy state and share a single quantum state.
Einstein soon extended Bose’s work to show that at extremely low temperatures “bosonic atoms” with even spins would coalesce into a shared quantum state at the lowest available energy. The requisite methods to produce temperatures low enough to test Einstein’s prediction did not become attainable, however, until the 1990s. One of the breakthroughs depended on the novel technique of laser cooling and trapping, in which the radiation pressure of a laser beam cools and localizes atoms by slowing them down. (For this work, French physicist Claude Cohen-Tannoudji and American physicists Steven Chu and William D. Phillips shared the 1997 Nobel Prize for Physics.) The second breakthrough depended on improvements in magnetic confinement in order to hold the atoms in place without a material container. Using these techniques, Cornell and Wieman succeeded in merging about 2,000 individual atoms into a “superatom,” a condensate large enough to observe with a microscope, that displayed distinct quantum properties. As Wieman described the achievement, “We brought it to an almost human scale. We can poke it and prod it and look at this stuff in a way no one has been able to before.”
BECs are related to two remarkable low-temperature phenomena: superfluidity, in which each of the helium isotopes 3He and 4He forms a liquid that flows with zero friction; and superconductivity, in which electrons move through a material with zero electrical resistance. 4He atoms are bosons, and although 3He atoms and electrons are fermions, they can also undergo Bose condensation if they pair up with opposite spins to form bosonlike states with zero net spin. In 2003 Deborah Jin and her colleagues at JILA used paired fermions to create the first atomic fermionic condensate.
BEC research has yielded new atomic and optical physics, such as the atom laser Ketterle demonstrated in 1996. A conventional light laser emits a beam of coherent photons; the
